Observation of a superparamagnetic breakdown in gadolinium chloride filled double-walled carbon nanotubes
نویسندگان
چکیده
In this article, the magnetic properties of gadolinium chloride-filled double-walled carbon nanotubes (GdCl3@DWNTs) in temperature range 2-300 K are explored. The temperature-dependent phonon frequencies G-band were studied from 80-300 to investigate effect on ordering. Temperature-dependent susceptibility measurements show that GdCl3@DWNTs sample has a pronounced superparamagnetic phase 83 K. dependence frequency for filled tubes exhibited distinct difference compared pristine nanotubes, where sharp hardening at low temperatures was observed. A correlation between onset superparamagnetism and abrupt verified. characterized by finite remnant magnetization 300 which decreased as lowered because presence discontinuous nanoparticles, providing contribution an S-shaped non-saturating hysteresis loop 2 Remarkably, superparamagnetism, marked bifurcation point, occurred roughly same showed approximately 80 K, indicating close modes spin clusters.
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ژورنال
عنوان ژورنال: AIP Advances
سال: 2021
ISSN: ['2158-3226']
DOI: https://doi.org/10.1063/9.0000128